Photocatalytic removal of o-chlorophenol by Using a Mixture of Modified Fly Ash and TiO2 Nanoparticles

Authors

  • Alireza Mesdaghinia Professor, Department of Environmental Health Engineering, School of Public Health & Water Quality Research Centre, Institute for Environmental Research, Tehran University of Medical Sciences, Tehran, Iran
  • Mohammad Malakootian Professor, Environmental Health Engineering Research Center & Department of Environmental Health, School of Public Health, Kerman University of Medical Sciences, Kerman, Iran
  • Shima Rezaei MSc, Environmental Health Research Center, Kurdistan University of Medical Sciences, Sanandaj, Iran
Abstract:

Abstract Background: Photocatalytic process is used as a suitable method for o-chlorophenol removal. In this study, the efficiency of a mixture of modified fly ash and TiO2 nanoparticles in photocatalytic removal of o-chlorophenol was evaluated. Methods: After acid washing of fly ash, the absorbent was oxidized with potassium permanganate. Then, the substrate mixture of modified fly ash and TiO2 nanoparticles was used for photocatalytic decomposition of o-chlorophenol. Results: The percentage of carbon increased from 77.94% to 86.52% after acid washing of fly ash and absorption efficiency increased from 58.8% up to 83.3%. During the oxidation of acid washed fly ash, absorption efficiency reached to 93.27%. Photocatalytic removal efficiency of o-chlorophenol by mixture of modified fly ash and TiO2 increased to 98.9%. Photocatalytic removal efficiency of o-chlorophenol by TiO2/UV and without use of fly ash was 78.7%. Conclusion: Industrial application of this method recommended because of the simple modification, high efficiency removal and prevention of environment pollution.  

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Journal title

volume 24  issue 2

pages  147- 158

publication date 2017-03-01

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